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16949-15-8

16949-15-8 Structure

16949-15-8 Structure
IdentificationMore
【Name】

Lithium borohydride
【CAS】

16949-15-8
【Synonyms】

LITHIUM BORANATE
LITHIUM BOROHYDRIDE
LITHIUM BORON HYDRIDE
LITHIUM TETRAHYDRIDOBORATE
LITHIUM TETRAHYDROBORATE
Borate(1-), tetrahydro-, lithium
Borate(1-),tetrahydro-,lithium
borohydruredelithium
LiBH4
Lithiumboranat
Lithiumborhydrid
Lithiumtetrahydridoborat
tetrahydro-borate(1-lithium
LITHIUM BOROHYDRIDE, HYDROGEN STORAGE G&
LITHIUM BOROHYDRIDE, 2.0M SOLUTION IN TE TRAHYDROFURAN
Lityium borohydride
Lithium borohydride, 2M solution in tetrahydrofuran
Lithiumborohydride,95%
lithium borohydride solution
Lithiumtetrahydroborat
【EINECS(EC#)】

241-021-7
【Molecular Formula】

BH4Li
【MDL Number】

MFCD00011088
【Molecular Weight】

21.78
【MOL File】

16949-15-8.mol
Chemical PropertiesBack Directory
【Appearance】

WHITE POWDER
【mp 】

280 °C
【bp 】

66°C/760mmHg
【density 】

0.896 g/mL at 25 °C
【Fp 】

−1 °F
【storage temp. 】

water-free area
【Sensitive 】

Air & Moisture Sensitive
【Merck 】

14,5525
【CAS DataBase Reference】

16949-15-8(CAS DataBase Reference)
【NIST Chemistry Reference】

Lithium tetrahydroborate(16949-15-8)
【EPA Substance Registry System】

16949-15-8(EPA Substance)
Safety DataBack Directory
【Hazard Codes 】

F,T,C
【Risk Statements 】

R14/15:Reacts violently with water, liberating extremely flammable gases .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable.
【Safety Statements 】

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
【RIDADR 】

UN 3399 4.3/PG 1
【WGK Germany 】

2
【RTECS 】

ED2725000
【F 】

10-21
【HazardClass 】

4.3
【PackingGroup 】

I
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Diethyl ether-->Sodium borohydride-->Lithium bromide
【Preparation Products】

1-AMINO-CYCLOPROPANEMETHANOL-->(S)-4-BOC-MORPHOLINE-3-CARBOXYLIC ACID-->5-(AMINOMETHYL)-1-METHYLPYRROLIDIN-2-ONE-->3,5-Dimethoxybenzylamine-->Thiophene-2-ethylamine-->BENZYL 4-(BROMOMETHYL)TETRAHYDRO-1(2H)-PYRIDINECARBOXYLATE-->1H-Azepine-3-carboxylicacid,hexahydro-,methylester(9CI)-->2,4-DIMETHOXYPHENETHYLAMINE-->Methyl 3-formylbenzoate
Hazard InformationBack Directory
【General Description】

A white to grayish crystalline powder.
【Reactivity Profile】

LITHIUM BOROHYDRIDE(16949-15-8) is a strong reducing agent. Is easily ignited and burns vigorously once ignited. Reacts on contact with water or acids to form hydrogen gas and corrosive products. Reaction with limited amounts of water or moisture may cause ignition after a delay [Gaylord, 1965, p. 22].
【Air & Water Reactions】

Likely to ignite when moistened with water [Lab. Gov. Chemist 1965].
【Health Hazard】

Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution.
【Fire Hazard】

Produce flammable gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard.
Material Safety Data Sheet(MSDS)Back Directory
【msds information】

lithium borohydride(16949-15-8).msds
Well-known Reagent Company Product InformationBack Directory
【Acros Organics】

Lithium borohydride, 4M (10 wt.%) solution in THF, AcroSeal?(16949-15-8)
【Alfa Aesar】

Lithium borohydride, 95%(16949-15-8)
【Sigma Aldrich】

16949-15-8(sigmaaldrich)
【TCI AMERICA】

Lithium Borohydride  (ca. 3mol/L in Tetrahydrofuran)(16949-15-8)
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