Identification | More | 【Name】
Ethyl methacrylate | 【CAS】
97-63-2 | 【Synonyms】
ETHYL 2-METHYLPROPENOATE ETHYL METHACRYLATE Ethyl-α-methyl acrylate METHACRYLIC ACID ETHYL ESTER RARECHEM AL BI 0124 2-Methyl-2-propenoic acid ethyl ester 2-methyl-2-propenoicacid,ethylester 2-methyl-2-propenoicaciethylester 2-Methylacrylic acid, ethyl ester 2-methyl-prop-2-enoicacidethylester 2-Propenoicacid,2-methyl-,ethylester EMA Ethyl 2-methacrylate Ethyl 2-methyl-2-propenoate Ethyl 2-methylacrylate Ethyl-.alpha.-methylacrylate ethyl2-methacrylate ethyl2-methylacrylate Ethyl-alpha-methyl acrylate ethylalpha-methylacrylate | 【EINECS(EC#)】
202-597-5 | 【Molecular Formula】
C6H10O2 | 【MDL Number】
MFCD00009161 | 【Molecular Weight】
114.14 | 【MOL File】
97-63-2.mol |
Chemical Properties | Back Directory | 【Appearance】
colourless liquid with an unpleasant odour | 【mp 】
-75 °C
| 【bp 】
118-119 °C(lit.)
| 【density 】
0.917 g/mL at 25 °C(lit.)
| 【vapor density 】
>3.9 (vs air)
| 【vapor pressure 】
15 mm Hg ( 20 °C)
| 【refractive index 】
n20/D 1.413(lit.)
| 【Fp 】
60 °F
| 【storage temp. 】
Refrigerator (+4°C) + Flammables area | 【Stability:】
Polymerizes in the presence of light or heat. Incompatible with peroxides, oxidizing agents, bases, acids, reducing agents, halogens and amines. Flammable. | 【Water Solubility 】
4 g/L (20 ºC) | 【BRN 】
471201 | 【CAS DataBase Reference】
97-63-2(CAS DataBase Reference) | 【NIST Chemistry Reference】
2-Propenoic acid, 2-methyl-, ethyl ester(97-63-2) | 【EPA Substance Registry System】
97-63-2(EPA Substance) |
Safety Data | Back Directory | 【Hazard Codes 】
F,Xi | 【Risk Statements 】
R11:Highly Flammable. R36/37/38:Irritating to eyes, respiratory system and skin . R43:May cause sensitization by skin contact. | 【Safety Statements 】
S9:Keep container in a well-ventilated place . S16:Keep away from sources of ignition - No smoking . S29:Do not empty into drains . S33:Take precautionary measures against static discharges . | 【RIDADR 】
UN 2277 3/PG 2
| 【WGK Germany 】
1
| 【RTECS 】
OZ4550000
| 【HazardClass 】
3 | 【PackingGroup 】
II | 【HS Code 】
29161490 | 【Hazardous Substances Data】
97-63-2(Hazardous Substances Data) |
Hazard Information | Back Directory | 【General Description】
A colorless moderately toxic liquid with an acrid odor. Flash point of 70°F. Boiling point 278°F. Vapors irritate the eyes and respiratory system. Less dense than water. Not soluble in water. Used to make polymers and other chemicals. | 【Reactivity Profile】
May polymerize if heated for prolonged periods or accidentally contaminated. If polymerization takes place inside a container, the container may violently rupture. Can react with oxidizing materials. When heated to decomposition ETHYL METHACRYLATE(97-63-2) emits irritating fumes and acrid smoke [Sax, 9th ed., 1996, p. 1576]. | 【Air & Water Reactions】
Highly flammable. A very dangerous fire and explosion hazard. Not soluble in water. | 【Health Hazard】
Inhalation may cause irritation of the mucous membrane. Ingestion causes irritation of mouth and stomach. Contact with liquid irritates eyes and skin. | 【Fire Hazard】
Behavior in Fire: Sealed containers may rupture explosively if hot. Heat can cause a violent polymerization reaction with rapid release of energy. Vapors are heavier than air and can travel to a source of ignition and flash back. |
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