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99-65-0

99-65-0 Structure

99-65-0 Structure
IdentificationMore
【Name】

1,3-Dinitrobenzene
【CAS】

99-65-0
【Synonyms】

1,3-DINITROBENZENE
M-DINITROBENZENE
1,3-dinitro-benzen
1,3-Dinitrobenzol
2,4-Dinitrobenzene
3-dinitrobenzene
Benzene, m-dinitro-
Binitrobenzene
Dwunitrobenzen
dwunitrobenzen(polish)
m-dinitro-benzen
m-dnb
meta-dinitrobenzene
nsc-7189
1,3-DINITRO BENZENE MI
m-dimitrobenzene
1,3-DINITROBENZENE, 1000MG, NEAT
1,3-DINITROBENZENE OEKANAL, 250 MG
1 3-DINITROBENZENE 98% (GC)
M-DinitrobenzeneGr
【EINECS(EC#)】

202-776-8
【Molecular Formula】

C6H4N2O4
【MDL Number】

MFCD00007222
【Molecular Weight】

168.11
【MOL File】

99-65-0.mol
Chemical PropertiesBack Directory
【Appearance】

orange to yellow crystalline powder
【mp 】

86 °C
【bp 】

297 °C(lit.)
【density 】

1.575
【Fp 】

150 °C
【storage temp. 】

2-8°C
【Stability:】

Stable. Incompatible with reducing agents, oxidizing agents, strong bases. May explode if heated.
【Water Solubility 】

500 mg/L (20 ºC)
【Merck 】

14,3273
【BRN 】

1105654
【CAS DataBase Reference】

99-65-0(CAS DataBase Reference)
【NIST Chemistry Reference】

Benzene, 1,3-dinitro-(99-65-0)
【EPA Substance Registry System】

99-65-0(EPA Substance)
Safety DataBack Directory
【Hazard Codes 】

T+,N,T,F
【Risk Statements 】

R26/27/28:Very Toxic by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R40:Limited evidence of a carcinogenic effect.
R36/37/38:Irritating to eyes, respiratory system and skin .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable.
【Safety Statements 】

S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S27:Take off immediately all contaminated clothing .
S16:Keep away from sources of ignition - No smoking .
【RIDADR 】

UN 3443 6.1/PG 2
【WGK Germany 】

3
【RTECS 】

CZ7350000
【HazardClass 】

6.1
【PackingGroup 】

II
【Hazardous Substances Data】

99-65-0(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Sulfuric acid -->Nitric acid-->Benzene-->Sodium sulfite-->Sodium metabisulfite-->Nitrobenzene-->Benzenesulfonic acid sodium salt-->1,4-DINITROBENZENE-->1,2-Dinitrobenzene
【Preparation Products】

Nitrobenzene-->1,3-Dichlorobenzene-->3-Nitroaniline-->m-Anisidine-->2,3-Dichloro-1,4-naphthoquinone-->Emodin-->2,3,5-TRIMETHYL-1,4-BENZENE DIAMINE-->2-Nitrobenzenesulfenyl chloride-->2-Nitrobenzenesulfonamide
Hazard InformationBack Directory
【General Description】

Yellow solid with a slight odor. Sinks in water.
【Reactivity Profile】

All three isomers have similar properties and may react vigorously with oxidizing materials. Their reaction with nitric acid (nitration) will lead to a mixture of trinitrobenzenes possessing high-explosive properties [Urbanski, 1967, vol. 3, p. 290]. If heat and reaction conditions of the nitration are not controlled, detonation comparable to TNT may occur [Anon., J. R. Inst. Chem., 1960, 84, p. 451]. Mixture of 1,3-dinitrobenzene with tetranitromethane was found highly explosive [Urbanski, 1964, vol. 1, 592]. 1,2-dinitrobenzene is a severe explosion hazard when shocked or exposed to heat or flame. When heated to decomposition all dinitrobenzens emit toxic fumes of nitrogen oxides [Sax, 9th ed., 1996, p. 1374].
【Air & Water Reactions】

Slowly mixes with water.
【Health Hazard】

Inhalation or ingestion causes loss of color, nausea, headache, dizziness, drowsiness, and collapse. Eyes are irritated by liquid. Stains skin yellow; if contact is prolonged, can be absorbed into blood and cause same symptoms as for inhalation.
【Fire Hazard】

Behavior in Fire: May explode
Material Safety Data Sheet(MSDS)Back Directory
【msds information】

1,3-Dinitrobenzene(99-65-0).msds
Spectrum DetailBack Directory
【Spectrum Detail】

1,3-Dinitrobenzene(99-65-0)IR1
1,3-Dinitrobenzene(99-65-0)IR2
1,3-Dinitrobenzene(99-65-0)MS
1,3-Dinitrobenzene(99-65-0)13CNMR
1,3-Dinitrobenzene(99-65-0)Raman
1,3-Dinitrobenzene(99-65-0)1HNMR
1,3-Dinitrobenzene(99-65-0)IR3
Well-known Reagent Company Product InformationBack Directory
【Alfa Aesar】

1,3-Dinitrobenzene, 99% (dry wt.), may cont. up to ca 5% water(99-65-0)
【TCI AMERICA】

1,3-Dinitrobenzene,>99.0%(GC)(99-65-0)
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