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CAS No. | 10025-87-3 |
Chemical Name: | Phosphorus oxychloride |
Synonyms: | OPCl3;POCl3;oxychloride;Fosforoxychlorid;Phosphorylchlorid;fosforoxychloride;Phosphoroxidchlorid;PHOSPHOROXYCHLORIDE;PHOSPHORYL CHLORIDE;oxychloridfosforecny |
CBNumber: | CB5218244 |
Molecular Formula: | Cl3OP |
Formula Weight: | 153.33 |
MOL File: | 10025-87-3.mol |
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Phosphorus oxychloride Property |
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density : |
1.675 g/mL at 20 °C(lit.)
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vapor density : |
5.3 (vs air)
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vapor pressure : |
104 mm Hg ( 50 °C)
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refractive index : |
n20/D 1.461
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Water Solubility : |
reacts exothermically |
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Sensitive : |
Moisture Sensitive |
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Stability:: |
Stable. Reacts violently with water. Incompatible with many metals, alcohols, amines, phenol, DMSO, strong bases. |
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Phosphorus oxychloride Chemical Properties,Usage,Production |
Chemical Properties
colourless liquid |
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General Description
A colorless fuming liquid with a pungent odor. Density 14.0 lb / gal. Very toxic by inhalation and corrosive to metals and tissue. Used in gasoline additives and hydraulic fluids. |
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Reactivity Profile
Phosphorus oxychloride is water reactive. Incompatible with strong oxidizing agents, alcohols, bases (including amines). May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Combining the chloride with zinc dust caused immediate ignition, due to the formation of phosphine gas which ignites, [Mellor, 1940, Vol. 8, 1025]. An exotherm starting with the mixing of Phosphorus oxychloride with acetone (a ketone) lead to an explosion, may behave similarly with other ketones, [Organic Process Research and Development, Vol.4, No. 6,200, "Phosphorus oxychloride and Acetone: An Incompatibility Investigation Using ARC."] |
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Health Hazard
Health Hazards : This poison is toxic by inhalation and ingestion and is strongly irritating to skin and tissues. It causes burns of the mucous membranes of the mouth and digestive tractand may be fatal. |
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Fire Hazard
Poisonous, corrosive, and irritating gases are generated when Phosphorus oxychloride is heated or is in contact with water. Phosphorus oxychloride may ignite other combustible materials (wood, paper, oil, etc.). Phosphorus oxychloride reacts violently with water. When heated to decomposition, Phosphorus oxychloride emits toxic fumes of chlorides and oxides of phosphorus; Phosphorus oxychloride will react with water or steam to produce heat and toxic and corrosive fumes. Incompatible with carbon disulfide; N,N-dimethylformamide; 2,5-dimethylpyrrole; 2,6-dimethyl- pyridine N-oxide; dimethylsulfoxide; Ferrocene-1,1-dicarboxylic acid; water; and zinc. Do not store with combustible materials, particularly fibrous organic materials, or with electrical or other equipment that can be corroded. Reacts violently with moisture. |
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Phosphorus oxychloride Preparation Products And Raw materials |
Raw materials
Distillation equipment
Sulfur dioxide
Chlorine
Oxygen
Phosphorus pentachloride
Phosphorus trichloride
White phosphorus
Silicon dioxide
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Preparation Products
2,4-DICHLOROTHIENO[3,2-D]PYRIMIDINE
DICAPTHON
2,2'-BITHIOPHENE-5-CARBOXALDEHYDE
5-METHYL-2-METHYLSULFANYL-PYRIMIDINE
BENZALDEHYDE NITROGEN MUSTARD
2-Trifluoromethylbenzylsulfonyl chloride
4,6-Dichloro-5-methoxypyrimidine
2-CHLORO-4-METHYLQUINOLINE-3-CARBONITRILE
4-(4-(BIS-(2-CHLOROETHYL)AMINO)BENZYLIDENE-2-PHENYL-OXAZOLINE-5-ONE
HEXAFLUOROGLUTARIC ANHYDRIDE
6-N-HEXYLAMINOPURINE
Thieno[3,2-d]pyrimidine, 2,4-dichloro-
Starch, hydrogen phosphate, 2-hydroxypropyl ether
2,6-Dichloro-4,8-dipiperidinopyrimidino[5,4-d]pyrimidine
2,4-Dichloro-5-nitropyrimidine
Disodium 4-nitrophenylphosphate
SALICYLIC ACID 4-TERT-BUTYLPHENYL ESTER
Tris(2-ethylhexyl) phosphate
2-ETHOXY-1-NAPHTHALDEHYDE
Chloroambucil
4-Chloro-7-azaindole
Basic Blue 7
2-(Chloromethyl)-5-propoxypyridine
Niclosamide
2-Chloro-4-methylpyrimidine
4-Chloro-3,5-dinitrobenzaldehyde
6-CHLORO-5-CYANO-4-METHOXYMETHYL-3-NITRO-2-PICOLINE
2-Chloro-3',4'-dihydroxyacetophenone
2,4,6-Trichloropyridine
DISTARCH PHOSPHATE
Quinazoline, 2-methyl- (6CI,7CI,8CI,9CI)
Acetylated Dishtarch Phosphate
PYRIDINE-3-SULFONYL CHLORIDE
4-(Dimethylamino)benzophenone
2-Chloro-5-thiophenecarboxaldehyde
P-TOLYL-ACETYL CHLORIDE
CHROMONE-3-CARBOXALDEHYDE
3-CHLORO-1H-INDAZOLE
4-TRIFLUOROMETHYLBENZYLSULFONYL CHLORIDE
2-CHLOROLEPIDINE
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Phosphorus oxychloride Suppliers Global( 191)Suppliers |
Supplier | Tel | Fax | Email | Country | ProdList | Advantage |
Zhengzhou Alfachem Co., Ltd.
| 0371- 53732842;13383863444 QQ:1065526125 | 0371-86239377 | gekun@alfachem.cn | CHINA |
886
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55
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Nanjing Huang Tai Pharmaceutical Technology Co. Ltd.
| 025-58803135 18136483526 | 025-58803650 | 3237333966@qq.com | CHINA |
1832
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58
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Nanjing Xiezun Chemical Co., Ltd.
| 025-85629050 13912997845 | 025-85629050 | tian_zun@126.com | CHINA |
77
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60
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Shanghai Song Yuan Chemical Technology Co., Ltd.
| 86-021-61533477;18521000990 | 86-021-33275113 | sonyuanchemical@163.com | CHINA |
6708
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50
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Alfa Aesar
| 400-610-6006; 021-67582000 | 021-67582001/03/05 | saleschina@alfa-asia.com | CHINA |
30333
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84
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JinYan Chemicals(ShangHai) Co.,Ltd.
| 13817811078,021-50426030 | 86-021-50426522,50426273 | sales@jingyan-chemical.com | CHINA |
10108
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60
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Shanghai Science Bio-Pharmaceutical Co. Ltd.
| 021-57872719,13918702962/13482412995 | 021-57872719 QQ:1823739912 | market@freefluor.com | CHINA |
309
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60
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Jia Xing Isenchem Co.,Ltd
| 0573-85280080 18267390595 | 0573-85285100 | isenchem@163.com,QQ:1404038297 | CHINA |
9788
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66
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Secco work (Beijing) chemical technology co., LTD
| 010-69755668; 62507480 | 010-69755668 | 1139670422@qq.com | CHINA |
3551
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54
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Shanghai GuangZan Chemical Technology Co., Ltd.
| 021-50426528 50426030 | 021-50426273 | shanghaiguangzan@163.com | CHINA |
12
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60
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Fosforoxychlorid
OPCl3
Oxychlorid fosforecny
oxychloridfosforecny
Phosphoroxidchlorid
Phosphortrichloridoxid
Phosphorus chloride oxide (POCl3)
Phosphorus oxytrichloride
phosphoruschlorideoxide(pocl3)
phosphorusoxytrichloride
phosphorustrichlorideoxide
Phosphorylchlorid
POCl3
Trichlorophosphine oxide
trichlorophosphineoxide
Trichlorophosphorus oxide
trichlorophosphorusoxide
10025-87-3
phosphoric trichloride
Phosphoryl oxychloride
PHOSPHORYL TRICHLORIDE
PHOSPHOROXYCHLORIDE
PHOSPHOROUS OXYCHLORIDE
PHOSPHORUS(V) OXIDE CHLORIDE
PHOSPHORUS(V) OXYCHLORIDE
PHOSPHORUS(V) TRICHLORIDE OXIDE
PHOSPHORYL CHLORIDE
PHOSPHORUS OXIDE CHLORIDE
PHOSPHORUS OXIDE TRICHLORIDE
Synthetic Reagents
Chlorination
C-X Bond Formation (Halogen)
PHOSPHORUS OXYCHLORIDE REAGENTPLUS(TM)&
PHOSPHORUS (V) OXYCHLORIDE, REAGENTPLUS, 99%
PHOSPHORUS OXYCHLORIDE, 99.999%
PhosphorousOxychlorideForSynthesis
Cl3OP
Phosphorusoxychloride,98+%
Phosphorusoxychloride,elec.gr.(99.999%-P)PURATREM
PHOSPHORUSOXYCHLORIDE,HIGHPURITY
PHOSPHORUSOXYCHLORIDE,REAGENT
PHODPHORUS OXYCHLORIDC
fosforoxychloride
Inorganics
Fosforoxychlorid [Czech]
Oxychlorid fosforecny [Czech]
Phosphorus oxychloride [UN1810] [Corrosive]
Phosphorus(V) oxychloride, 99.999% (metals basis)
Phosphorus(V) trichloride oxide, 99.999% (metals basis)
Phosphorus oxide chloride, Phosphoryl chloride
Phosphorus(V) oxide chloride, Phosphoryl chloride
phosphorus oxychloride for high purity
phosphollJs oxychloride
Phosphorus oxychloride,99%
Phosphorus oxychloride
Phosphorus oxychlori
metal oxyhalide
Phosphorus oxitrichloride
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