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Dimethyl sulfide

CAS No.75-18-3
Chemical Name:Dimethyl sulfide
Synonyms:DMS;ME2S;(CH3)2S;Exact-S;FEMA 2746;Thiopropane;2-Thiopropane;2-THIAPROPANE;Dimethylsulfid;thiobis-methan
CBNumber:CB6478393
Molecular Formula:C2H6S
Formula Weight:62.13
MOL File:75-18-3.mol
Dimethyl sulfide Property
mp : −98 °C(lit.)
bp : 38 °C(lit.)
density : 0.846 g/mL at 25 °C(lit.)
vapor density : 2.1 (vs air)
vapor pressure : 26.24 psi ( 55 °C)
refractive index : n20/D 1.435(lit.)
FEMA : 2746
Fp : −34 °F
storage temp. : 2-8°C
Merck : 14,6123
Stability:: Stable. Incompatible with strong oxidizing agents. Highly flammable - note low boiling point, low flash point, and wide explosion limits. Mixtures with air are potentially explosive. Incompatible with strong oxidizing agents. Use in UK regulated by LPG Regulations 1978 in accordance with HSE guidance note CS17.
CAS DataBase Reference: 75-18-3(CAS DataBase Reference)
NIST Chemistry Reference: Dimethyl sulfide(75-18-3)
EPA Substance Registry System: Methane, thiobis-(75-18-3)
Safety
Hazard Codes : F,Xn,Xi
Risk Statements : 11-22-37/38-41-36
Safety Statements : 7-9-16-29-33-36/39-26
RIDADR : UN 1164 3/PG 2
WGK Germany : 1
RTECS : PV5075000
F : 13
HazardClass : 3
PackingGroup : II
Hazardous Substances Data: 75-18-3(Hazardous Substances Data)

Dimethyl sulfide Chemical Properties,Usage,Production

Chemical Properties
Clear colorless liquid
General Description
A clear colorless to straw colored liquid with a disagreeable odor. Flash point less than 0°F. Less dense than water and slightly soluble in water. Vapors are heavier than air.
Air & Water Reactions
Highly flammable. Slightly soluble in water.
Reactivity Profile
Organosulfides, such as Dimethyl sulfide, are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Dimethyl sulfide rapidly decomposes dibenzoyl peroxide explosively in the absence of solvent, [J. Org. Chem., 1972, 37, 2885]. The sulfide also decomposes xenon difluoride explosively at ambient temps, [J, Chem Soc., 1984, 2827]. Interaction of Dimethyl sulfide and oxygen is explosive at 210°C and above, [Atmos. Environ., 1967, 1, 491-497]. A delayed explosion occurred in a system containing nitric acid, Dimethyl sulfide, and 1, 4-dioxane, even with cooling with liquid nitrogen, [Chem. Abs., 1972, 76, 13515].
Health Hazard
Inhalation causes moderate irritation of upper respiratory system. Contact of liquid with eyes causes moderate irritation. Repeated contact with skin may extract oils and result in irritation. Ingestion causes nausea and irritation of mouth and stomach.
Dimethyl sulfide Preparation Products And Raw materials
Raw materials
HYDROGEN SULFIDE ANION STANDARD - SULFATE Sodium thiomethoxide Carbon disulphide LIGNIN, ALKALI Aluminum oxide Dimethyl sulfate
Preparation Products
Ethyl 5-[3-(4,6-dimethoxy pyrimidyl-2-yl)ureido]methylpyrazolyl-4-carboxylic ester Dimethyl chlorothiophosphate Dimethoate Procarbazone sodium Fluorescent Brightener 185 Fluticasone propionate Pazufloxacin ETHYL 3-FUROATE CARBOPHENOTHION Parathion-methyl Methidathion 4-AMINO-2-(METHYLTHIO)-6-PYRIMIDINOL Orthene Fenitrothion Ranitidine hydrochloride Azamethiphos FENOTHIOCARB O,O-Dimethyl S-methylcarbamoylmethyl phosphorothioate Mifepristone Ketorolac ISOFENPHOS Phosmet 4-Methylthio-4-methyl-2-pentanone 5-CARBOXYCYTOSINE Methyl [(dimethoxyphosphinothioyl)thio]acetate CYANOPHOS Fipronil 4-AMINO-2-(METHYLTHIO)PYRIMIDINE-5-CARBOXYLIC ACID Dimethyl sulfoxide Ammonium O,O-dimethyl dithiophosphate 3-FURANMETHANOL 4-AMINO-2-METHYLSULFANYL-PYRIMIDINE-5-CARBOXYLIC ACID ETHYL ESTER Malathion WL 108477 FLOSEQUINAN CHLOROMETHYL METHYL SULFIDE Dimethylphosphorodithioate 5-HYDROXYMETHYLCYTOSINE Aminoguanidinium sulphate
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