Litium

Litium Property

mp : 180 °C(lit.) bp : 1342 °C(lit.) density : 0.534 g/mL at 25 °C(lit.) storage temp. : water-free area form : wire Water Solubility : REACTS Merck : 13,5542 Stability:: Stability Stable, but reacts violently with water. Store under oil. CAS DataBase Reference: 7439-93-2(CAS DataBase Reference) NIST Chemistry Reference: Lithium(7439-93-2) EPA Substance Registry System: Lithium(7439-93-2)

Safety

Hazard Codes : Xi,C,F Risk Statements : 36/38-34-14/15-23 Safety Statements : 8-43-45-43C-36/37/39-26 RIDADR : UN 3264 8/PG 3 WGK Germany : 2 RTECS : OJ5540000 F : 10 HazardClass : 4.3 PackingGroup : I Hazardous Substances Data: 7439-93-2(Hazardous Substances Data)

Litium Chemical Properties,Usage,Production

Chemical Properties soft silver metal General Description A soft silvery metal that is normally grayish white due to oxide formation. Spontaneous ignition is likely if heated to melting point. Air & Water Reactions Highly flammable. Is readily ignited by and reacts with most extinguishing agents such as water, carbon dioxide, and carbon tetrachloride [Mellor 2, Supp 2:71. 1961]. Reacts with water to form caustic Litium hydroxide and hydrogen gas (H2). Litium is spontaneously flammable in air if heated to 180°C if the surface of the metal is clean. Reactivity Profile Burns in air, oxygen, nitrogen, hydrogen, and carbon dioxide. The reactions can become extremely violent at higher temperatures. The disposition to ignite of surfaces of molten Litium exposed to any of these gases is increased by the presence of Litium oxides and nitrides. Litium reacts avidly with water to generate gaseous hydrogen and a solution of Litium hydroxide (a caustic). Contact with halogenated hydrocarbons can produce extremely violent reactions, especially on impact [Haz. Chem. Data 1966]. Boron trifluoride reacts with incandescence when heated with Litium [Merck 11th ed. 1989]. Maleic anhydride decomposes explosively in the presence of Litium [Chemical Safety Data Sheet SD-88. 1962, Chem. Haz. Info. Series C-71. 1960]. Chlorine vapors and Litium react producing a luminous flame [Mellor 2, Supp. 1:380. 1956]. The product of the reaction between Litium and carbon monoxide, Litium carbonyl, detonates violently with water, igniting the gaseous products [Mellor 2, Supp. 2:84. 1961]. The reaction of Litium and ferrous sulfide starts around 260°C with subsequent rise in temperature to 950° C [Mellor 2, Supp. 2:80. 1961]. A truck, which was carrying Litium batteries, sodium dithionite and derivatives of cyanide, caught fire; multiple explosions occurred as the cargo was exposed to the air. Health Hazard Contact with eyes causes caustic irritation or burn. Incontact with skin Litium reacts with body moisture to cause chemical burns: foil, ribbon, and wire react relatively slowly.

Litium Preparation Products And Raw materials

Raw materials Argon Lithium chloride

Preparation Products Empenthrin 2-(HYDROXYETHYL)-6-METHYLPYRIDINE 2-DIPHENYLPHOSPHINO-6-METHYLPYRIDINE BIS(P-TOLYL)PHOSPHINE OXIDE Chlorodimethylphenylsilane Diphenylphosphine Diphenyl-2-pyridylphosphine Lithium peroxide (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (+)-DIOP Diphenylphosphine oxide 2-[2-(DIPHENYLPHOSPHINO)ETHYL]PYRIDINE Bis(diphenylphosphino)methane Estradiol (XYL)2P(O)H Cinmethylin 2-(DIPHENYLPHOSPHINO)ETHYLTRIETHOXYSILANE 2-(DIPHENYLPHOSPHINO)ETHYLAMINE Tris(triphenylphosphine)ruthenium(II) chloride (-)-DIOP 4,6-DIMETHYL-PYRIDINE-2-CARBOXYLIC ACID [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride 1,3-Bis(diphenylphosphino)propane (+)-(3R,4R)-BIS(DIPHENYLPHOSPHINO)-1-BENZYLPYRROLIDINE 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride (1R,2R)-(+)-1,2-Diphenylethylenediamine 1,3-DIMETHYL-4-PHENYL-4-PIPERIDINOL TRIS(TRIMETHYLSILYL)SILANE (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Methoxydienone 2-(4-Methylphenyl)pyridine [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Cyclopentanol 13-ethyl-3-methoxygona-2,5(10)-dien-17beta-ol 2,6-DICHLORO-5-FLUORONICOTINOYL CHLORIDE (3S,4S)-(-)-1-BENZYL-3,4-BIS(DIPHENYLPHOSPHINO)PYRROLIDINE 11b,21-Dihydroxy-2'-methyl-5'bH-pregna-1,4-dieno[17,16-d]oxazole-3,20-dione 21-acetate Leaf alcohol (2S,4S)-(-)-N-BOC-4-Diphenylphosphino-2-diphenylphosphinomethyl-pyrrolidine Gemfibrozil

Litium Suppliers      Global( 133)Suppliers      BELGIUM 1 CANADA 1 CHINA 72 Europe 2 GERMANY 4 INDIA 2 JAPAN 7 RUSSIA 1 Slovakia 1 SWITZERLAND 1 UNITED KINGDOM 7 USA 34 Global 133

Supplier Tel Fax Email Country ProdList Advantage MINS GROUP CO.,LIMITED 18653327685 0533-6721845 yuan19870503@126.com CHINA 20 58 J & K SCIENTIFIC LTD. -- -- jkinfo@jkchemical.com;market3@jkchemical.com CHINA 96847 76 Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-59487313(Beijing) +86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com CHINA 40407 62 Alfa Aesar 400-610-6006; 021-67582000 021-67582001/03/05 saleschina@alfa-asia.com CHINA 30333 84 Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820 86 (10) 60270825 dtftchem@sina.com CHINA 4703 62 Energy Chemical 021-58432009 / 400-005-6266 021-58436166-800 info@energy-chemical.com CHINA 44198 61 Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028 +86-10-82967029 sales@ouhechem.com CHINA 10815 60 JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030 86-021-50426522,50426273 sales@jingyan-chemical.com CHINA 10108 60 Secco work (Beijing) chemical technology co., LTD 010-69755668; 62507480 010-69755668 1139670422@qq.com CHINA 3551 54 Adamas Reagent, Ltd. 400-600-9262 021-51701678 mc@titansci.com CHINA 13697 59