Tiglic acid

Tiglic acid Suppliers list
Company Name:AILY INTL CHEMICAL CORP LTD  Gold
Tel:+86-2583208295 18913388297
Email:ben@ailybiotech.com
Products Intro: Product Name:Tiglic acid
CAS:80-59-1
Purity:98% Package:25kg
Company Name:Shanghai URChem Limited  Gold
Tel:086-21-68416098 68416096
Email:danny@urchem.com; todd@urchem.com; sunfriderman@msn.com
Products Intro: Product Name:Tiglic acid
CAS:80-59-1
Purity:99%Min. HPLC Package:25kg纸板桶或参照客户要求
Company Name:J & K SCIENTIFIC LTD.  
Tel:400-666-7788 +86-10-82848833
Email:jkinfo@jkchemical.com;market3@jkchemical.com
Products Intro: Product Name:trans-2,3-DiMethylacrylic acid
CAS:80-59-1
Purity:98% Package:100G,25G,500G
Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel:+86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-59487313(Beijing)
Email:sh@meryer.com
Products Intro: Product Name:Tiglic Acid
CAS:80-59-1
Purity:>98.0%(GC)(T) Package:25g;500g Remarks:T0246
Company Name:Arden pharmaceutical &chemical Co., Ltd  
Tel:+86-(0)533-3595900 13793319233
Email:info@chems.com.cn
Products Intro: Product Name:Tiglic acid
CAS:80-59-1
Purity:≥99% Package:25KG/Drum
Tiglic acid Basic information
Product Name:Tiglic acid
Synonyms:(E)-2-METHYL-2-BUTENOIC ACID;E-2,3-DIMETHYLACRYLIC ACID;FEMA 3599;2,3-DIMETHYLACRYLIC ACID;2-METHYL-TRANS-2-BUTENOIC ACID;2-METHYL-2-BUTENOIC ACID;2-METHYLBUT-2-ENOIC ACID;2-METHYLCROTONIC ACID
CAS:80-59-1
MF:C5H8O2
MW:100.12
EINECS:201-295-0
Product Categories:Aromatic Cinnamic Acids, Esters and Derivatives
Mol File:80-59-1.mol
Tiglic acid Structure
Tiglic acid Chemical Properties
mp 61-64 °C(lit.)
bp 95-96 °C12 mm Hg(lit.)
density 0.969 g/mL at 25 °C(lit.)
FEMA 3599
Fp 101°C
storage temp. Refrigerator (+4°C)
Water Solubility SOLUBLE IN HOT WATER
Merck 14,9433
BRN 1236500
CAS DataBase Reference80-59-1(CAS DataBase Reference)
NIST Chemistry Reference2-Butenoic acid, 2-methyl-, (E)-(80-59-1)
EPA Substance Registry System2-Butenoic acid, 2-methyl-, (2E)-(80-59-1)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-36/37/38
Safety Statements 26-36/37/39-45-24/25-27
RIDADR UN 3261 8/PG 2
WGK Germany 2
RTECS GQ5430000
HazardClass 8
PackingGroup III
HS Code 29161980
Hazardous Substances Data80-59-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Tiglic acid English
ACROS English
SigmaAldrich English
ALFA English
Tiglic acid Usage And Synthesis
Chemical PropertiesWHITE TO BEIGE CRYSTALLINE POWDER AND CHUNKS
UsageTiglic acid is the stable isomer of angelic acid. Tiglic acid was found as glyceride in croton oil, as butyl ester in the oil of the Roman camomile, and as geranyl tiglate in oil of geranium. Tiglic a cid is formed during the charcoaling of maple wood.
General DescriptionA white lustrous flaked solid with a fruity or spicy odor. About the same density as water and slightly soluble in water. May burn if heated to high temperatures. May severely irritate skin, eyes, lungs or mucous membranes.
Air & Water ReactionsSlightly soluble in water.
Reactivity ProfileTIGLIC ACID is a carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in Tiglic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.
Health HazardTOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardNon-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Tiglic acid Preparation Products And Raw materials
Preparation ProductsALLYL TIGLATE-->BENZYL TIGLATE-->Ethyl tiglate
Tag:Tiglic acid(80-59-1) Related Product Information
Fumaric acid Acetonitrile Methyl Paraquat dichloride Tiglic acid DL-Thioctic acid trans,trans-2,4-Undecadienal 2-Methyl-2-butene phosphoric acid Diethyl methylmalonate Citric acid Maleic acid Crotonic acid Crotonic acid Folic acid Methanol ASCORBICACID ACETIC ACID