Ethyl bromoacetate

Ethyl bromoacetate Property

mp : -38 °C bp : 159 °C(lit.) density : 1.506 g/mL at 25 °C(lit.) vapor pressure : 2.6 mm Hg ( 25 °C) refractive index : n20/D 1.451(lit.) Fp : 118 °F Stability:: Stable. Combustible. Incompatible with strong oxidizing agents, water, strong acids. CAS DataBase Reference: 105-36-2(CAS DataBase Reference) NIST Chemistry Reference: Acetic acid, bromo-, ethyl ester(105-36-2) EPA Substance Registry System: Acetic acid, bromo-, ethyl ester(105-36-2)

Safety

Hazard Codes : T+ Risk Statements : 26/27/28 Safety Statements : 26-45-7/9-1/2 RIDADR : UN 1603 6.1/PG 2 WGK Germany : 1 RTECS : AF6000000 F : 19 HazardClass : 6.1 PackingGroup : II HS Code : 29159080 Hazardous Substances Data: 105-36-2(Hazardous Substances Data)

Ethyl bromoacetate Chemical Properties,Usage,Production

Chemical Properties colourless to light yellow liquid Usage Ethyl Bromoacetate, is used in the synthesis of metabolites of carcinogenic PAHs. Used in the preparation of steroidal antiestrogens through cyclic condensation. A reactant in the preparation of antim icrobial and antioxidant coumarinyloxymethyl-thiadiazolone. General Description A clear, colorless liquid (b.p. 318°F). Flash point 47°C. A lachrymator. Toxic by ingestion, inhalation and skin absorption; a strong irritant of the skin. Insoluble in water and soluble in alcohol, benzene, and ether. Specific gravity of 1.5. Air & Water Reactions Flammable. Insoluble in water. Reactivity Profile Ethyl bromoacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Health Hazard TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. Fire Hazard HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Ethyl bromoacetate Preparation Products And Raw materials

Raw materials Bromoacetic acid

Preparation Products ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE ETHYL 3-AMINOBENZOFURAN-2-CARBOXYLATE 5-BROMO-1-BENZOFURAN-2-CARBALDEHYDE 3-METHYLBENZOFURAN-2-CARBONYL CHLORIDE ethyl 2-(2-aminothiazol-5-ylthio)acetate 3-METHYLBENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER 3-O-TOLYL-PROPIONALDEHYDE Ethyl 2-oxocyclopentylacetate 5-BROMO-1-BENZOFURAN-2-CARBOXYLIC ACID 2-Phenyl-1H-indole-1-acetic acid ,97% (R)-3-Aminoquinuclidine dihydrochloride 3,4-DIMETHYLTHIENO[2,3-B]THIOPHENE-2-CARBALDEHYDE (5-BROMO-1-BENZOFURAN-2-YL)METHANOL 3-(4-CHLORO-PHENYL)-PROPIONALDEHYDE 3,5-DIMETHYL-BENZOFURAN-2-CARBOXYLIC ACID Piperazin-2-one Rhodanine-3-acetic acid 3-CHLOROPHENOXYACETYL CHLORIDE ETHYL METHANESULFONYLACETATE 6-BROMO-1-BENZOFURAN-2-CARBOXYLIC ACID 4-(TRIFLUOROMETHYL)PHENOXYACETIC ACID (4-METHYL-PIPERAZIN-1-YL)-ACETIC ACID METHYL5,5,5-TRIFLUORO-4-OXOPENTANOATE (4-PHENYL-PIPERAZIN-1-YL)-ACETIC ACID trans-2-Octen-1-ol 2-METHYLCYCLOPROPANECARBOXYLIC ACID MORPHOLINE-4-CARBOTHIOAMIDE (S)-(+)-3-Quinuclidinol Ethyl(4-butyry-2,3-dichloro)phenoxyacetate Ethyl 3,5-dimethylbenzofuran-2-carboxylate ,95% 4-CHLORO-8-FLUORO-5H-PYRIMIDO[5,4-B]INDOLE (4-FLUOROPHENOXY)ACETYL CHLORIDE 2-(CARBOXYMETHOXY)BENZOIC ACID ethyl 2-(2-phenyl-1H-indol-1-yl)acetate ETHYL 3,3-DIETHOXYPROPIONATE 3-COUMARANONE ETHYL 2-(5-FORMYL-2,4-DIMETHYL-1H-PYRROL-3-YL)ACETATE quinuclidine-3-carboxylic acid GERANIC ACID (R)-3-Quinuclidinol hydrochloride

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